One Piece: Season 1, Episode 110
1 - 110: Merciless Mortal Combat! Luffy vs. Crocodile!
After escaping from Rain Dinners, the Straw Hats and Vivi cross the desert to Alubarne, where the final battle will take place. Crocodile, however, manages to catch Luffy, beginning the first round of their battle.
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