Bleach: Season 1, Episode 207

1 - 207: 12th Division's New Captain, Urahara Kisuke

Urahara Kisuke has now become Captain of 12th squad but his new Vice-Captain Hiyori Sarugaki refuses to accept him. He even goes so far as to let her win in a duel against him to try and gain her confidence. However, after a pep talk from Shinji he decides to just be himself and stop worrying about it.